If you're looking at something along the lines of a Sigelei 150, the IPV4, or the Snowwolf like I think you are, then 20A batteries are sufficient.
One very important thing to point out... ...you shouldn't use your old batteries in a series mod when you can help it. It's standard practice to marry batteries for series mods and only use them in series mods. If they aren't discharging evenly, then they tend to burn one another out. The weaker cell gets charged by the stronger one. Reverse charging is not good for your batteries. It has a cascading effect. The more you run them like that, the harder the strain gets.
You'll get a longer lifespan and better capacity using batteries that are exactly the same age, have seen exactly the same wear and have always been charged together. Its not super dangerous if you don't always use married batteries, but it's still much more ideal in the long run. Batteries are cheap. Drop the 24 bucks on two pairs of new batteries for better, more consistent performance.
High-powered series mods only pull the current they need to generate the raw wattage at the batteries' voltage... ...and they don't need much when you have 8v of push. Voltage can be converted to current as needed, so you can pull 20 amps from your batteries in order to push 38 amps to your atty at a lower voltage.
This also means that current draw increases as battery voltage decreases. To run at 150w, a reggie box will pull 20 amps from fresh batteries and 27 amps from batteries approaching the low voltage cutoff. For 100w, it's 13 amps fresh and 20 depleted. At 75w, its only 10 amps fresh and 14 depleted.
25r's would be fine a fine choice if you're mostly vaping at 100w or less. Any more than that and you are going to start approaching or even surpassing the 20A CDR at some point, but not to a battery venting degree. The strain is going to be pretty minimal for new batteries. Capacity will decrease noticeably, though I'm willing to bet that most 30A batteries still will not last as long. You can run newer, trustworthy 20A cells up to 150w with no worries.
I have 25r's and VTC5's, which I often run at or above 100w. The Samsungs are the winners, hands down. They last much longer.
For 100w and below, I'd highly recommend the Samsung 30Q's. They're 3000mah, 15A batteries, but they can handle 20 amps more than adequately. When you start pulling over 15 amps, I believe the capacity dips to around 2500mah, which still isn't too bad. And they last much, much longer than the 25r's at under 100w. If you want a battery that will last forever at a lower wattage, but will still be usable at a higher wattage, it's a great battery.